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Chocolate Shown to Combat Aging

Life by chocolate, or death by chocolate?

Feb 2004

There is an increasing outflow of pro-chocolate PR, and much of the excitement centers around antioxidants. Fruits and vegetables contain antioxidants, which have the ability to temper free radicals, and thereby help to lower the risk of heart disease, some cancers and other age-related maladies. More and more people are trying to bombard their diets with the antioxidant fountain of youth.

Enter chocolate, stage left. Chocolate, derived from the beans of the cacao tree, is brimming with antioxidants, in much higher concentrations than other produce. This could be because chocolate is highly concentrated, undiluted by the water that makes fruits and vegetables so juicy.

How it works: the Biology

Big picture: Although we need oxygen to live, oxygen is dangerous. It's like using dynamite to light a stove. Humans have evolved to breathe oxygen-containing air, but it's a volatile substance. Not surprisingly, plants have opted to avoid oxygen and to release it whenever possible. That could be why trees can live so much longer; their bodies aren't constantly bombarded with destructive oxygen.

According to a USDA article ("Vitamins and Minerals, Free Radicals and Aging" by Jack Saari - link to article), the most popular explanation of aging illness is the "oxidative theory," or "free radical theory." This theory says that, though oxygen is necessary to human life, it is also increasingly harmful as we age.

A natural byproduct of metabolism, oxygen can be transformed into free radicals. Free radicals are atoms or molecules that have an unpaired electron. They are usually very unstable, trying to bind with anything that will give them their missing electron. (source). These free radicals wreak havoc on protein, DNA and fat molecules, upon which our bodies depend.

The USDA article explains that to combat free radical damage, our bodies have antioxidant enzymes. These enzymes weaken over time, however, and the body's defenses can be boosted by the ingestion of antioxidant-containing foods, or foods that contain vitamins that boost antioxidants in the body.

For example, vitamins C and E have been shown to act as antioxidants, which means that they bind with the free radicals, thereby disarming their destructive potential.

Antioxidant foods are rated by their ORAC, or "oxygen radical absorbance capacity," which is a food's ability to calm free radicals. And this brings us back to chocolate.

Dark chocolate, per 100 grams, has twice the ORAC of milk chocolate, four times the ORAC of raisins and about ten times the ORAC of raspberries, according to data (link to data) from the USDA and the Journal of the American Chemical Society.

ORAC per 100 grams

13,120 Dark Chocolate
6,740 Milk Chocolate
5,770 Prunes
2,830 Raisins
2,400 Blueberries
1,770 Kale
980 Brussel Sprouts
739 Red Grapes
400 Corn
390 Eggplant


Dr. Ronald Prior, a USDA nutrition researcher, has studied the antioxidant potential of chocolate.

"Dark chocolate is going to be on the high end, higher than most fruits and vegetables," Prior said.

He stressed the importance of eating a variety of antioxidant-containing foods, however. "It's the combination that's going to be beneficial," Prior said.

Dark, Milk or White Chocolate?

Dark.

One recent study, "Plasma antioxidants from chocolate" (Nature, 8/03), showed that eating plain, dark chocolate increased antioxidant capacity. These gains, however, were significantly reduced if the chocolate was milk chocolate or consumed with milk. The study concluded that milk may erase the benefits of eating dark chocolate.

Another study, "Chocolate and Blood Pressure in Elderly Individuals with Isolated Systolic Hypertension" (Journal of the American Medical Association, 8/03), focused on white chocolate versus dark chocolate. The study compared 13 men and women, ages 55-64, who had untreated, mild hypertension.

Participants were randomly assigned 14 days of either 90 grams of white chocolate or 90 grams of dark chocolate. Within 10 days of the 14-day experiment, those eating dark chocolate had significantly lowered their blood pressure, while those eating white chocolate had not benefited.

However, the results did not last beyond the chocolate intake; participants' blood pressures returned to the pre-chocolate level within two days of stopping chocolate intake.
Source: http://www.consumerhealthjournal.com/articles/chocolate.htm

 


Sweet! Study says dark chocolate has benefits

Flavonoids can lower blood pressure, researchers say

20 July 2005

WASHINGTON (Reuters) -- Dark chocolate can not only soothe your soul but can lower blood pressure too, researchers reported Monday.

The study, published by the American Heart Association, joins a growing body of research that show compounds found in chocolate called flavonoids can help the blood vessels work more smoothly, perhaps reducing the risk of heart disease.

"Previous studies suggest flavonoid-rich foods, including fruits, vegetables, tea, red wine and chocolate, might offer cardiovascular benefits, but this is one of the first clinical trials to look specifically at dark chocolate's effect on lowering blood pressure among people with hypertension," said Jeffrey Blumberg of Tufts University in Boston, who led the study.

"This study is not about eating more chocolate," Blumberg added. "It suggests that cocoa flavonoids appear to have benefits on vascular function and glucose sensitivity."

Scientists are far from being able to make specific recommendations for patients based on their research on chocolate, and nutritionists have urged people to be cautious because chocolate is high in fat, sugar and calories.

Blumberg and colleagues at the University of L'Aquila in Italy studied 10 men and 10 women with high blood pressure.

For 15 days, half ate a daily 3.5 ounce (100 gram) bar of specially formulated, flavonoid-rich dark chocolate, while the other half ate the same amount of white chocolate.

Then each group "crossed over" and ate the other chocolate.

"White chocolate, which has no flavonoids, was the perfect control food because it contains all the other ingredients and calories found in dark chocolate," Blumberg said.

"It's important to note that the dark chocolate we used had a high level of flavonoids, giving it a slightly bittersweet taste. Most Americans eat milk chocolate, which has a low amount of these compounds."

Writing in the journal Hypertension, Blumberg's team said when the volunteers ate the special dark chocolate, they had a 12 mm Hg decrease in systolic blood pressure (the top number in a blood pressure reading) and a 9 mm Hg decrease in diastolic blood pressure (the bottom number) on average.

Blood pressure did not change when the volunteers ate white chocolate.

"This is not only a statistically significant effect, but it's also a clinically meaningful decline," Blumberg said. "This is the kind of reduction in blood pressure often found with other healthful dietary interventions."

Eating dark chocolate also seemed to improve how the body used insulin, and reduced low density lipoprotein (LDL) or "bad" cholesterol by about 10 percent on average.

"The findings do not suggest that people with high blood pressure should eat lots of dark chocolate in lieu of other important blood pressure-reduction methods, such as medication and exercise," Blumberg said. "Rather, we are identifying specific flavonoids that can have a benefit on blood pressure and insulin sensitivity."
 
A Dark Chocolate a Day Keeps the Doctor Away

Daily Dark Chocolate Good for the Heart, Loaded With Flavoniods


By Daniel DeNoon
WebMD Medical News Reviewed By Brunilda Nazario, MD
on Tuesday, June 01, 2004

Here's news that's hard not to like. Eating a small, 1.6-ounce bar of dark chocolate every day is good for you. Very good for you, find Mary Engler, PhD, RN, of the University of California, San Francisco, and colleagues.

Now here is a medical experiment you would love to volunteer for. Engler's team divided 21 healthy adults into two groups. One group got a Dove Dark Chocolate bar every day for two weeks. Like other dark chocolate bars with high-cocoa content, this one is loaded with something called epicatechin. Epicatechin is a particularly active member of a group of compounds called plant flavoniods. Flavoniods keep cholesterol from gathering in blood vessels, reduce the risk of blood clots, and slow down the immune responses that lead to clogged arteries.

The second group that didn't get Dove bars wasn't totally left out. They, too, got dark chocolate bars. But their treats had the flavoniods taken out.

All subjects underwent high-tech evaluation of how well the blood vessels dilate and relax -- an indictor of healthy blood vessel function. Blood vessel stiffness indicates diseased vessels and possible atherosclerosis. Those who got the full-flavonoid chocolate did significantly better. Why? Blood tests showed that high levels of epicatechin were coursing through their arteries.

"This is the longest clinical trial to date to show improvement in blood vessel function from consuming flavonoid-rich dark chocolate daily over an extended period of time," Engler says in a news release. "It is likely that the elevated blood levels of epicatechin triggered the release of active substances that ... increase blood flow in the artery. Better blood flow is good for your heart."

Why Dark Chocolate Is Different
Not all chocolate is created equal. Dark chocolate contains a lot more cocoa than other forms of chocolate. And standard chocolate manufacturing destroys up to half of the flavoniods. But chocolate companies have now learned to make dark chocolate that keeps up to 95% of its flavoniods.

Sure, this seems like a scam. Can't you get more and better flavoniods from other foods? Surprisingly, the answer is "not really." Engler says that dark chocolate contains more flavoniods than any other food -- including green tea, black tea, red wine, and blueberries.

"Many people don't realize that chocolate is plant-derived, as are the fruits and vegetables recommended for a healthy heart," Engler says.

While a little dark chocolate is good, a lot is not better. Chocolate still is loaded with calories. If you're going to eat more chocolate, you'll have to cut back somewhere else. And remember that a balanced diet -- and plenty of exercise -- is still the key to heart health.

Engler's study was funded by the University of California, San Francisco, School of Nursing. The American Cocoa Research Institute, a nonprofit group funded by the chocolate industry, provided the chocolate used in the study.

The findings appear in the June issue of the Journal of the American College of Nutrition. Engler previously reported the findings at the 2002 Scientific Sessions of the American Heart Association and at the Experimental Biology 2003 meeting.

SOURCES: Engler, M.B. Journal of the American College of Nutrition, June 2004; vol 23: pp 197-204. News release, University of California, San Francisco.
 
Chocolate for Life
Are you a chocoholic? Don't worry - that's a good thing. Chocolate may be one of the most functional foods out there

By Willow Lawson
Feb 2003

Cliched as it is, maybe that box of Valentine's Day chocolates isn't such a bad idea.

In recent years, studies have absolved chocolate of causing acne, cavities and high cholesterol levels. But a new study goes even further, proving that chocolate may be one of the most functional foods out there, even a great brain saver. Of course, you don't need any persuading that it's probably the most delicious as well.

Chocolate turns out to be a good source of antioxidants - those beloved chemicals known for their cell-protecting properties. Antioxidants scavenge and fight off free radicals, wildly reactive rogue molecules of oxygen that damage cell membranes and the DNA, which contains the cells basic operating instructions. Free radicals aid and abet heart disease by oxidizing the "bad" (LDL) cholesterol, leading to hardened arteries. Free radicals are also linked to cancer and degenerative diseases in all parts of the body.

The battle between antioxidants and free radicals takes place at the most basic level in our bodies. Free radicals have an odd number of electrons, which makes them unstable; they steal electrons wherever they can find them. Antioxidants have the ability to donate an electron, neutralizing free radicals without becoming free radicals themselves.

The brain is particularly susceptible to free radical damage because it is exposed to a large amount of oxygen; as the body's most metabolically active organ, it consumes about 20% of the body's oxygen, although it totals only 2% of our body weight. Free radicals enter our bodies through pollution, fried food and even just normal metabolic processes of the body.

The fatty membranes that cover all brain cells are particularly subject to oxidative damage. Free radical damage is implicated in cognitive decline and memory loss as people age and in Alzheimer's disease.

A steady level of antioxidants - including vitamins C and E and beta carotene - is linked to strong memories, according to studies in the Netherlands and Australia.

The body gets antioxidants both by manufacturing them and consuming them in foods. They are found most abundantly in fruits and vegetables, but all plants have at least a small amount of antioxidants. Dietary sources of these chemicals are particularly important during stressful times, when body loses its ability to make them.

Berries, tea, garlic and wine are all well-known sources of antioxidants. But cocoa beans top them all, says Joe Vinson, Ph.D., a chemistry professor at the University of Scranton in Pennsylvania. His research shows that cocoa beans are the most potent source of polyphenols, a large subgroup of antioxidants. Scientists have identified around 6,000 antioxidants so far, says Vinson. About 4,000 fall into the category of polyphenols.

Because polyphenols are found in the cocoa bean - not the milk, cream, sugar or other additives - the darker the chocolate, the better. As a general rule, antioxidants are found in the pigments of fruits and veggies, so the more colorful the food, the richer in antioxidants.

By weight, cocoa powder packs the most antioxidant punch, according to Vinson's research. "It is loaded!" the chemist says. It has twice as many antioxidants as dark chocolate, which in turn has twice as many as milk chocolate. White chocolate has no antioxidants at all.

The amount of polyphenols in a serving of dark chocolate is comparable to that in a cup of black tea and higher than in a glass of red wine, things long touted as great sources of antioxidants.

Hot chocolate is the best bet for those looking for the antioxidant punch without the paunch that cocoa butter could bring. But it's important to make the hot chocolate from scratch, with pure cocoa powder, milk and sugar, says Vinson. His studies have shown that homemade hot chocolate has five times as many antioxidants as a store-bought mix.

So think of chocolate as a brain food.

"People thank me all the time for telling them that chocolate is good for them, ," says Vinson. "And really it is. I eat a little bit of chocolate every day."
 
Chocolate

Apr 2001


What's in the cocoa bean?

Cocoa is a rich source of procyanidin flavonoids, including epicatechins and its derivatives. The antioxidant content is significantly higher than tea. Oligomeric polyphenols in cocoa are stronger antioxidants than monomeric polyphenols in tea. Oligomeric polyphenols inhibit reactive oxygen species which can damage cell membranes leading to diseases such as arteriosclerosis, cancer and the ageing process.

After an acute chocolate meal, plasma concentrations of epicatechin and plasma antioxidant capacity increase compared to an acute white chocolate meal. The increase in antioxidant capacity has been observed by a decrease in lipid oxidation by-products. These results suggest that flavonoids can be absorbed in quantities to influence the body’s defence parameters.

Any health benefits?

Antioxidants

Finally, some good news for chocolate lovers. It is not as bad for us as we think. Recent studies have indicated that certain ingredients in chocolate may play a role in preventing heart disease and cancer. Cocoa beans (one of the main ingredients of chocolate) contain over 600 plant chemicals including anti-oxidants which may protect against such diseases. Most of these studies however, have been conducted on cocoa flavoured beverages, not chocolate, which may be misleading. It is worth considering these studies, however, as the findings prove to be very interesting.

Cocoa beans contain a type of phytochemical (anti-oxidant) called polyphenols, which may have a role in the prevention of certain diseases. Polyphenols help guard the body's cells from damage by free radicals. The particular substances arousing so much interest are catechins which are a type of polyphenol. It is these catechins which aid resistance against degenerative diseases such as cancer and heart disease. Catechins can also be found in fruits and vegetables, but the body needs to capture as many different types of catechins as possible such as those found in tea and chocolate. Dark chocolate has higher concentrations of catechins due to higher levels of cocoa.

Feeding studies in human showed that LDL cholesterol in the blood taken 2 hours post consumption of chocolate was less likely to oxidise. One study demonstrated that chocolate polyphenols affected platelet activation proteins. When platelets which were exposed to chocolate polyphenols were stimulated with epinephrine (known to cause platelet aggregation) aggregation decreased, thus reducing the risk of blood clot formation. More evidence is needed on how these findings translate to heart health.

Saturated fat

Although chocolate has often been condemned due to it's high saturated fat content, the most predominant saturated fat in chocolate, stearic acid, does not have the same cholesterolaemic effect as other saturated fats. The major lipid in chocolate consists of oleic acid, stearic and palmitic acids. Several studies indicate that stearic acid has a neutral effect on blood lipids. However, stearic acid may activate clotting factor VII, may increase lipoprotein Lp(a) concentration and may impair blood clot break down (fibrinolysis) (AJCN 1999; 70: 951). However, cocoa butter appears to decrease platelet activity, potentially beneficial for cardiovascular health. Stearic acid can be found in meat fat, some margarines, and chocolate.

Dark chocolate versus milk chocolate

A recent study reported by Vlachopoulos at the 2004 European Society of Cardiology demonstrated for the first time how chocolate improved the function of blood vessels, allowing them to dilate, which would help prevent the formation of potentially damaging clots. The study showed that eating 100 grams of dark chocolate improved vessel function in 17 healthy young adults for at least three hours.
Dark chocolate contains high levels of an antioxidant called flavonoids. This study sheds new light on how the mechanism might work, by protecting blood vessels from the damaging effects of unstable oxygen compounds called free radicals. Free radicals attack other atoms to stabilise themselves by stealing an electron, and in the process can damage cells. The study did not include milk chocolate, but the same benefits might not be gained from eating milk chocolate. In 2003, scientists reported that dark chocolate increased levels of antioxidants in the blood by nearly 20% where as milk chocolate did not have the same effect. It is thought that milk may interfere with the absorption of antioxidants from the chocolate.

Conclusion

We must still remember though that chocolate is a high-fat food and must be consumed in moderation as part of an otherwise nutritious diet. It is also advisable to obtain the benefits of catechins from cocoa (e.g. as hot chocolate, mocha coffee) rather than chocolate because plain cocoa does not have the fat content of chocolate. Traditional Mexican cuisine uses dark chocolate in savoury white meat and vegetable dishes (see below). Chocolate eaten this way has a lower energy density. Tea also contains catechins (although not as many as chocolate and cocoa) and may therefore provide some of the same benefits as consuming cocoa or chocolate without the fat.